Thanks for your replies! It looks like I'll be fine then.
Martin, as far as hardware is concerned, I don't really have anything other than what I have installed now, which is really only all the internal upgrades, which should obviously work just fine.
I use Steam for gaming, but then again I don't. I have 24GB's worth of games installed, but I must confess that I have played them maybe once or twice. 4-5 versions of HalfLife, BioShock, Counter Strike, etc. The usual suspects I assume. Do any of you think they will work on x64? I kind of doubt it, but I'd gladly give them up for the speed of 64-bit.
bill bolton wrote:The only way you are going to find out for all your 32 bit applications is to see what happens!
Bill, yes, I agree. And I made up my mind that I'll do exactly that, see what will happen tonight.

I have everything ready, so I'll clone the HDD before I reformat it and install Vista Ultimate x64 only. Then I'll just install each app one by one, as well as SP1, which sped up my current 32-bit installation quite a bit, by the way!
Hmm...speaking of SP1. Should I maybe just let it install whatever Windows Updates it has available through Windows Update, or run SP1 right from the start. I have the full installer (x64 version is about 736MB's worth), so all the hotfixes, updates, etc., should be in it!? I have already found out playing around with VUx64 in this apparently ill-advised dual-boot configuration that I need to get the drivers myself. I pretty much have them all in one place, so I'm good to go on that front as well.
You also mentioned the x86 Program Files folder. I was actually pleasantly surprised. IE7 is also installed in both x86 and x64. I assume the installer will "see" which folder to install whatever app it is that I want to install, and use the correct folder...
Funny you should mention your WWAN manager software. I am going to get an HSUPA card when I get back to the U.S., and I will also want to run AT&T's WWAN manager for it. But that's in the future.
Software-wise, the most important are the various video playback software I use, all of which work great on x86. So those will be most interesting as far as the extent to which they will work. This is not like Steam and the games. lol...I need at least a few to work, so I can watch streaming video and Bluray's, DVD's, etc. without any problems. Also, plug-in's for Firefox are important. Oh well, we shall see...
One more thing. I've already noticed that the CPU temp's go up by 10-15C, and that was light usage for a relatively short period of time. Do you also see the temps go up noticeably? Mine usually hover in the mid-50's C, go up into the 60's, and will reach over 70C when I watch a movie, while scanning the hard drive for malware, for example. I don't want to mess up my CPU. Is 70C too hot? What temps are you getting?
Alright, thanks very much again!! If you, or anyone else, can think of anything to add that I ought to do (or avoid), please post. It'll be another 4-6 hours before I'll pull the trigger on this project.

15-inch Core 2 Duo ThinkPad T60p | Ivy-Bridge (Late-2012) Mac mini w/ quad Core i7-3615QM 2.3GHz, 16GB DDR3-1600MHz RAM, 240GB+180GB Intel 520 Series SATA III SSD's, 5x3TB Drobo 5D